Spain's Alejandro Valverde responded to losing the lead of the Volta a Catalunya because of a team penalty by winning the third stage on Wednesday.
England will not face New Zealand this year after a game between the All Blacks and the Barbarians at Twickenham on 4 November was confirmed.
Gareth Southgate suffered his first defeat in charge of England as Lukas Podolski's spectacular second-half winner provided a fitting farewell to his Germany career in Dortmund.
Chris Froome lost 46 seconds on Volta a Catalunya rival Alejandro Valverde as the Spaniard's Movistar team won stage two's team time trial.
Katie Taylor will continue her push towards a shot at a world title by facing former IBF super-featherweight challenger Milena Koleva on Saturday.
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